Partial Hydrogenation of Edible Oils without Formation of Trans-Fatty Acids
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Maj-Britt Macher |

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Background :
Large amounts, 20 million ton, of vegetable oils are hydrogenated
each year, mostly for the production of margarine and shortenings.
In the traditional process the poor solubility of hydrogen in
oil leads to a lack of hydrogen at the catalyst surface. This
causes positional and cis- / trans- isomerization of fatty acids.
From a medical point of view the trans- fatty acids are strongly
questioned and their formation should be minimized.
The project :
We add propane to the oil and hydrogen. By that, a substantially
homogeneous near- or supercritical mixture can be attained. Under
these conditions the transport resistances at the catalyst surface
are minimized. In this way extremely high reaction rates are
reached and the product contains only small amounts of trans-
fatty acids. In this project the reaction conditions (pressure,
temperature, composition, catalyst) will be optimized.
Ph.D Theses
Macher, M-B. (2001) Supercritical Hydrogenation of Vegetable
Oils.
PhD
Thesis; Chalmers University of Technology: Gothenburg,
Sweden
Page maintained by
svh@harrod-research.se Updated: 2001-05-10
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